We explain and exploit the random matrix formulation of the Loschmidt echo for the XX spin chain, valid for multiple domain wall initial states and also for a XX spin chain generalized with additional interactions to more neighbours. For models with interactions decaying as
e−α∣∣l−j∣∣/∣∣l−j∣∣p+1, with p integer or natural number and α≥0, we show that there are third order phase transitions in a double scaling limit of the complex-time Loschmidt echo amplitudes. For the long-range version of the chain, we use an exact result for Toeplitz determinants with a pure Fisher-Hartwig singularity, to obtain exactly the Loschmidt echo for complex times and discuss the associated Stokes phenomena. We also study the case of a finite chain for one of the generalized XX models.